Furthermore, the reported data are, perhaps, the only systematic sets of conductivity values available so far for very dilute aqueous sulfuric acid, at <0.001 M. 5 The acid may behave quite differently in low-permittivity water at very high temperature under elevated pressure, see Ref. [ Citation 22 ], at which conditions the pentacoordinate.. The conductivity might be viewed relative to other electrolytes and by concentration. By concentration: Up to about 25% $\ce{H2SO4:H2O}$, conductivity increases fairly linearly with concentration, reaches a maximum at ~35%, and then drops precipitately (no pun intended)! And sulfuric acid has such "affinity" for water that oleum, or fuming sulfuric acid, has more $\ce{SO3}$ than $\ce{H2O}$.

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AChem's answer to Why does the graph of the electrical conductivity of sulfuric acid/water solutions have this knee in the ~85%-~92% range? includes this plot from Horace E. Darling in "Conductivity of sulfuric acid solutions" (Journal of Chemical & Engineering Data 9.3 (1964): 421-426.) and mentions:. There is a sharp increase in viscosity at 85%, which indicates there is a major structural.. Electrical conductivity is the most cost-effective technique for measuring oleum and sulfuric acid purity, which are critical parameters used to control process conditions and safeguard the process equipment in sulfuric acid manufacturing.. (392 °F) and suitable for use under high pressure up to 295 psig (2135 kPa [abs]) Process Connection.